The product-forming step in palladium-catalysed methoxycarbonylation of organic halides
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 817-818
- https://doi.org/10.1039/c39860000817
Abstract
Use of trimethylphosphine–palladium complexes renders the product-forming step in palladium-catalysed methoxycarbonylation of benzyl chloride or iodobenzene rate-determining and allows for its direct observation; the product-forming step is alcoholysis of an acylpalladium complex and not reductive elimination of a methoxycarbonylpalladium intermediate.Keywords
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