The rates of solvent aquation of a series of halogeno-cobalt(III) complexes
- 1 January 1966
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 19 (11) , 2051-2057
- https://doi.org/10.1071/ch9662051
Abstract
The rates of aquation and temperature coefficients of a series of homoisomeric cations ω-[CoX en dien]2+ (X = Cl, Br, I) together with those of the isomer ε-[CoCl en dien]2+ and the analogous cation [CoCl ibn cytam]2+ are recorded. A consideration of the factors determining the rates of these reactions leads to the conclusion that there is an element of bond making in the transition state.Keywords
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