Ground state of liquid helium in the Kirkwood superposition approximation
- 1 November 1976
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 14 (9) , 3937-3952
- https://doi.org/10.1103/physrevb.14.3937
Abstract
We calculate the ground-state energies and pressures for and (normal) using radial distribution functions which are solutions of the Born-Bogoliubov-Green-Kirkwood-Yvon (BBGKY) integral equation with the Kirkwood superposition approximation (KSA) used for the three-particle distribution function. We compare the BBGKY-KSA results with those obtained from the hypernetted chain equation, molecular dynamics, and experiment. We conclude that the BBGKY-KSA yields poor results for but at the lower densities offers a reasonable approximation to the molecular-dynamics results. The energies are obtained by means of the statistical cluster expansion of Wu and Feenberg and we discuss the convergence of the series. Further, we show that the familiar parametrized power-law form used for the pair function yields pressures consistent with the virial theorem.
Keywords
This publication has 25 references indexed in Scilit:
- Ground State of Two-Dimensional Liquid HeliumPhysical Review A, 1972
- Ground-State Energy of LiquidHe4Physical Review A, 1972
- Paired-Phonon Analysis for the Ground State and Low Excited States of Liquid HeliumPhysical Review B, 1969
- Triplet Correlations in Liquid HeliumPhysical Review B, 1969
- Density, Coefficient of Thermal Expansion, and Entropy of Compression of LiquidHe4under Pressure below 1.4°KPhysical Review B, 1967
- Ground State of Liquid Helium-4 and Helium-3Physical Review B, 1967
- Theory of the (Normal) Ground State of Liquid Helium ThreePhysical Review B, 1966
- Variational Method for the Ground State of LiquidPhysical Review Letters, 1966
- Theory of the Fermion LiquidPhysical Review B, 1962
- Approximation Methods in Classical Statistical MechanicsPhysical Review Letters, 1962