Nuclear magnetic resonance spectra of nitrosobenzenes. Anomalous chemical shifts in ortho-substituted nitrosobenzenes
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 1583-1586
- https://doi.org/10.1039/j29700001583
Abstract
The n.m.r. spectra of ortho-substituted nitrosobenzenes have been measured and the chemical shifts of o-aromatic, o-methyl, o-methoxyl, and o-t-butyl protons have been found to be anomalous. These anomalous chemical shifts are explained mainly in terms of the large magnetic anisotropy of the nitroso-group.Keywords
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