Domino Heck–C–H activation reaction of unsymmetrically substituted [3]cumulene
- 3 August 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 34,p. 3648-3650
- https://doi.org/10.1039/b607684j
Abstract
The Heck reaction of an unsymmetrically substituted [3]cumulene has been investigated. Although a carbonyl conjugated alkene is present, the arylpalladium species selectively inserts into the C3–4 double bond, and a subsequent C–H activation reaction with a neighboring phenyl group gives the indene derivatives with a tetrasubstituted olefin moiety.Keywords
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