Mono- and bis(tetrathiafulvaleno)hexadehydro[12]annulenesElectronic supplementary information (ESI) available: cyclic voltammograms of the annulenes 1 and 2. See http://www.rsc.org/suppdata/cc/b4/b407200f/

Abstract
Hexadehydro[12]annulenes annelated with one or two TTF units have been synthesized to investigate their π-amphoteric properties based on the TTF and [12]annulene moieties; these compounds show multi-redox potentials, solvatochromism and the formation of large sandwich complexes.

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