Hydrogen transfer and C–H activation in a dihydroiridium amido-alkene complex
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1278-1280
- https://doi.org/10.1039/c39870001278
Abstract
Dihydrogen addition to the alkene complex (5) is regiospecific and stereoselective; the dihydride mixture is converted into alkyl hydrides and ultimately into a chelation-controlled C–H insertion product (10).Keywords
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