A unique macrocyclic structure of tetrameric trimethyltin(IV) diphenylphosphinate, [Me3SnO2PPh2]4, containing a sixteen-membered Sn4O8P4 inorganic ring

Abstract
Trimethyltin(IV) diphenylphosphinate, Me3SnO2PPh2, is a macrocyclictetramer containing an Sn4O8P4 ring made up from trigonal bipyramidal O–SnMe3–O units interconnected by (nearly) tetrahedral diphenylphosphinato groups, O–PPh2–O, through oxygen-sharing.

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