The biosynthesis of echinulin: origins of the diastereotopic methyls in the 1,1-dimethylallyl group
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 879-880
- https://doi.org/10.1039/c39830000879
Abstract
In the biosynthesis of echinulin (1) the pro-S methyl of the 1,1-dimethylallyl group is derived predominantly (89%) from the methyl group of mevalonic acid.Keywords
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