Diterpenoids. 49. Syntheses of taxodione, royleanone and their analogues.

Abstract
Using the readily obtainable 11-nitrophenol 5 prepared by selective nitration of the 12-hydroxy ester 4, syntheses of taxodione (1), royleanone (2) and their analogues (7 and 8) having the methoxy-carbonyl group in place of the 4α-methyl group were accomplished.

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