Prescriptions and Ingredients for Controlled CC Bond Formation with Organometallic Reagents. New synthetic methods (5)
- 1 November 1974
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 13 (11) , 701-706
- https://doi.org/10.1002/anie.197407011
Abstract
Merits and drawbacks of known carbon‐carbon linking procedures are outlined. Two novel methods are discussed in some detail: the copper‐catalyzed alkylation of Grignard reagents and reactions with allylpotassium compounds. Both methods provide a very efficient access to saturated, unsaturated, as well as functionally substituted hydrocarbons and moreover permit an astonishing degree of regio‐ and stereoselective control of olefin synthesis.Keywords
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