Transformation of the cluster Pt3(µ-CO)3(PPh3)4into Pt5(µ-CO)5(CO)(PPh3)4upon impregnation onto inorganic supports
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 334-335
- https://doi.org/10.1039/c39830000334
Abstract
The impregnation of organic solutions of Pt3(µ-CO)3(PPh3)4 onto inorganic supports used for catalysis or chromatography has been shown to produce Pt5(µ-CO)5(PPh3)4, depending upon the nature of the support, its pre-treatment, and the solvent used; these observations are relevant to the preparation of cluster-derived catalysts.Keywords
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