A simple synthesis of cis- and trans-fused 14,15-dinoreudesmanolides
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 286-288
- https://doi.org/10.1039/c39870000286
Abstract
Three possible stereoisomers of 14,15-dinoreudesmanolide, the structure of which consists of an α-methylene-γ-lactone ring fused to a trans-decalin ring, have been synthesized from a dialdehyde monoacetal viaα-trimethylsilylmethyl-α,β-unsaturated esters.Keywords
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