Electrochemical Studies of Titanium in Molten Fluorides
- 1 January 1973
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 120 (9) , 1193-1199
- https://doi.org/10.1149/1.2403659
Abstract
The electrochemical reduction of Ti(IV) in molten at 500°C was studied by means of linear sweep voltammetry, chronopotentiometry, and chronoamperometry. The reduction of Ti(IV) to Ti(III) was found to proceed reversibly at both platinum and pyrolytic graphite electrodes; further reduction of Ti(III) to the metal was shown to be a reversible process involving alloy formation with the platinum electrode. Standard electrode potentials for the processes, , respectively (both vs. a unit mole fraction electrode).Keywords
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