New synthesis and isocyano-complexes of chloro(π-cyclopentadienyl)titanium(III)

1 January 1973

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.

No. 19,p. 1954-1957
https://doi.org/10.1039/dt9730001954

Abstract

A new synthesis of the complexes [Ti(cp)₂Cl]₂(I) and [Ti(cp)Cl₂]₂(II)via[Ti(cp)₂(CO)₂](cp =π-cyclopentadi-enyl) is reported. The reaction of complexes (I) and (II) with cyclohexyl isocyanide (C₆H₁₁NC) affords the first isocyano-complexes of titanium, [Ti(cp)₂Cl(C₆H₁₁NC)](V) and [Ti(cp)Cl₂(C₆H₁₁NC)₂](VI); complex (V) can also be obtained from the reaction between [Ti(cp)₂(CH₂Ph)Cl] and C₆H₁₁NC.

Keywords

TITANIUM