Chiral monolayer of self-assembled Δ-[Os(bpy)2L(Cl)]+ [bpy = 2,2′-bipyridyl, L = 1,2-bis(4-pyridyl)ethane] on a platinum electrode
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 111-112
- https://doi.org/10.1039/a606791c
Abstract
A chiral osmium complex, Δ-(2,2′-bipyridyl) [1,2-bis(4-pyridyl)ethane] chloroosmium Δ-[Os(bpy) 2 L(Cl)] + , is successfully self-assembled at a monolayer molecular level on a clean Pt electrode in non-aqueous solutions; the self-assembled Δ-[Os(bpy) 2 LCl] + ions show a phenomenally repulsive interaction with each other on Pt in chiral-field formation and also in the Os II –Os III redox reaction, while racemic complexes interact less repulsively with each other.Keywords
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