Grignard compound derived from isopropyl mesityl ketone containing trico-ordinate magnesium
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 14,p. 859-860
- https://doi.org/10.1039/c29700000859
Abstract
Evidence from cryoscopic determinations in naphthalene and benzene, elemental and hydrolytic analyses, i.r. and 1H n.m.r. spectra shows that the Grignard compound from isopropyl mesityl ketone orginally prepared by Fuson and his co-workers in 1939 is a monomeric enolate (III) containing trico-ordinate magnesium in contrast to the dimeric structure (I) found for the corresponding halogeno-derivatives from methyl mesityl ketone.Keywords
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