Novel complexes of uranium(V)
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 13,p. 759-760
- https://doi.org/10.1039/c29690000759
Abstract
Several new complexes of formally quinquevalent uranium, all but one of which have the general formula UCl5Lx, have been synthesized (the donor atoms in the organic ligands being N, P, As, S, Se, and Te) for which there is e.s.r. evidence suggesting that the lone UV electron is strongly delocalized on to the unsaturated organic moiety, perhaps into π-antibonding MO's.Keywords
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