Action Des Rayons Ionisants Sur Le Benzene Liquide Et Gazeux
- 1 January 1959
- journal article
- research article
- Published by Wiley in Bulletin des Sociétés Chimiques Belges
- Vol. 68 (1-3) , 89-101
- https://doi.org/10.1002/bscb.19590680109
Abstract
The action of alpha particles (5‐8 Mev) on liquid benzene at 30°C and on gaseous benzene at 100°C is followed by a spectrographic method for the reaction in the liquid phase and by manometric measurements for the study of gaseous products formation and of the reaction in the gas phase. In the two cases, within the experimental errors, the effects are proportional to the absorbed energy and are independent on the presence of the products and on the intensity of irradiation. This suggests that the reactions involve hot radicals and occur in the vicinity of the tracks. The yield of disappearance of the molecules in the gaseous reaction (Gdisap. = 4,23) is of the same order of magnitude as the yield found by Henry, Maxwell, White and Peterson for the alpha irradiation of benzene vapor at room temperature. The gaseous yield of the reaction in the liquid phase (Ggas = 0,173) is about three times more important than the yield found by other authors for the beta and gamma irradiation. This seems due to the greater density of ions and excited molecules along the track of the alpha particle.Keywords
This publication has 10 references indexed in Scilit:
- Scavenger Methods for Free Radical Detection in Hydrocarbon RadiolysisThe Journal of Physical Chemistry, 1958
- Identification of Products in the Radiolysis of Liquid BenzeneThe Journal of Physical Chemistry, 1958
- Effects of Phase on Reactions Induced by Radiation in Organic SystemsThe Journal of Physical Chemistry, 1958
- The Effect of Solutes on the Radiolysis of CyclohexeneThe Journal of Physical Chemistry, 1957
- Theory of Radiation Chemistry. III. Radical Reaction Mechanism in the Tracks of Ionizing RadiationsThe Journal of Chemical Physics, 1956
- Effect of Iodine on the Radiolysis of BenzeneThe Journal of Physical Chemistry, 1956
- Radiolysis of Hydrocarbon MixturesThe Journal of Physical Chemistry, 1952
- The Chemical Effects of α-Particles upon Some Hydrocarbons in the Vapor SystemsThe Journal of Physical Chemistry, 1952
- Radiation chemistry of pure organic compounds: benzene and benzene-d 6Discussions of the Faraday Society, 1952
- A Calculation of the Energy Absorbed in a Spherical Volume Containing a Gas-Radon MixtureThe Journal of Chemical Physics, 1950