Reaction of tricarbonylcycloheptatrieneiron with base: the tricarbonylcycloheptatrienyliron anion
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 21,p. 1390-1391
- https://doi.org/10.1039/c29710001390
Abstract
Tricarbonylcycloheptatrieneiron (1) exchanges stereoselectively with MeO– in MeOD immeasurably faster than the uncomplexed hydrocarbon; reaction of (1) with butyl-lithium in tetrahydrofuran gives the first reported complex of the cycloheptatrienyl anion.Keywords
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