Electric Strength and Molecular Structure of Saturated Hydrocarbon Liquids

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Abstract
A number of investigators have reported that the apparent electric strengths of straight‐chain hydrocarbon liquids increase in a regular manner with increasing molecular chain length. In a recent publication we have presented evidence that this phenomenon is an illustration of a kind of Paschen's law for liquids. An observed linear dependence of the electric strengths of such hydrocarbons upon density suggested that chain length variation merely provided a means of changing the electron mean free path in the liquid. In the present paper we describe the development of an improved technique for measuring electric strengths of liquids, and the application of this technique to a series of pure straight‐chain and branched‐chain liquid alkanes. As had been observed previously, the strengths of the straight‐chain members of the series exhibit a linear relationship with density. The introduction of branches into the hydrocarbon chain, however, results in a definite decrease in strength. Extension of the measurements to hydrocarbons of more complicated structure has apparently introduced a kind of fine structure. Measurement of the time dependence of electrical breakdown in liquid hydrocarbons shows that the formative time lag is relatively insensitive to changes in viscosity or molecular weight. For an electrode separation of 0.002 inch, it is approximately one microsecond.

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