Crystal and molecular structure of a novel bimetallocarborane anion
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 234-235
- https://doi.org/10.1039/c39740000234
Abstract
The bimetallocarborane, [Et4N][(η-C5H5)-Co-C2B8H10-Co-C2B8H10], which was prepared by the poly-hedral expansion of 1,6-C2B8H10 at –80°, was studied by single-crystal diffraction techniques; the anion was found to contain a bimetallic Co2C2B8H10 unit in which one cobalt atom was shared with a terminal C2B8H10 group.Keywords
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