The Structure of (11xi,12xi)-11,12-Di(7-drimen-11-oxy)-11,12-epoxy-7-drimene.
- 1 January 1977
- journal article
- research article
- Published by Danish Chemical Society in Acta Chemica Scandinavica
- Vol. 31b (1) , 51-55
- https://doi.org/10.3891/acta.chem.scand.31b-0051
Abstract
A new terpenoid, isolated from Drimys winteri Forst, was assigned the structure (11.xi.,12.xi.)-11,12-di(7-drimen-11-oxy)-11,12-epoxy-7-drimene on the basis of spectral and chemical data including hydrolysis to the known sesquiterpenoids drimenol and polygodial. The absolute configurations were established for all but 2 asymmetric centers, which were tentatively deduced from 13C and 1H NMR considerations.This publication has 0 references indexed in Scilit: