Homogeneous catalysis: use of chiral titanocene complexes for asymmetric catalytic Diels–Alder reactions
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1181-1182
- https://doi.org/10.1039/c39950001181
Abstract
A stable, chiral diaquo titanocene complex is an excellent catalyst for certain Diels–Alder reactions giving good enantioselectivity which indicates that catalysis occurs by metal rather than by proton activation of the dienophile.Keywords
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