Improved highly efficient synthesis of α,β-acetylenic ketones. Nature of the intermediate from the reaction of lithium acetylide with boron trifluoride etherate
- 31 December 1984
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 25 (23) , 2411-2414
- https://doi.org/10.1016/s0040-4039(01)81192-8
Abstract
No abstract availableKeywords
This publication has 25 references indexed in Scilit:
- A Simple Synthesis of Alkynyl Ketones via ThexylchloroboraneSynthesis, 1983
- Improved procedure for the asymmetric reduction of prochiral ketones by B-3-pinanyl-9-borabicyclo[3.3.1]nonaneThe Journal of Organic Chemistry, 1982
- Tilden Lecture. Carbon–carbon bond formation involving boron reagentsChemical Society Reviews, 1982
- Reduction of .alpha.,.beta.-acetylenic ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane. High asymmetric induction in aliphatic systemsJournal of the American Chemical Society, 1980
- Conjugate addition-elimination in the reaction of .beta.-1-alkynyl-9-borabicyclo[3.3.1]nonanes with 4-methoxy-3-buten-2-one and related derivatives. A convenient new route to conjugated enynonesThe Journal of Organic Chemistry, 1977
- Conjugate addition of B-1-alkynyl-9-borabicyclo[3.3.1]-nonanes to .alpha.,.beta.-unsaturated ketones. A convenient synthesis of .gamma.,.delta.-acetylenic ketonesJournal of the American Chemical Society, 1977
- Convenient stereospecific synthesis of terminal acetylenes via the treatment of lithium ethynyltrialkylborates with iodineThe Journal of Organic Chemistry, 1974
- Advances in the Chemistry of Ethynyl KetonesRussian Chemical Reviews, 1973
- The photochemistry of acetylenic compounds. The photochemical reduction of some conjugated acetylenic carbonyl compoundsJournal of the American Chemical Society, 1968
- The Preparation of Acetylenic Ketones Using Soluble Silver AcetylidesJournal of the American Chemical Society, 1956