Hydrothermal synthesis and crystal and molecular structure of a reduced, arsenic rich heteropolyanion, Na4[Mo4As6O20(OH)2]·9H2O
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 356-357
- https://doi.org/10.1039/c39930000356
Abstract
The hydrothermal reaction of Na3MoO4·2H2O, Mo metal, MnO3, H5As3O10, NaCl and H2O in the mole ratio 6 : 6 : 6 : 3 : 10 : 166 for 110 h at 180 °C yielded orange crystals of the sodium salt of the arsenic-rich MoV–AsIII polyanion cluster, Na4[Mo4As6O20(OH)2]·9H2O.Keywords
This publication has 6 references indexed in Scilit:
- Coordination chemistry of soluble metal oxides of molybdenum and vanadiumCoordination Chemistry Reviews, 1992
- Polyoxo alkoxides of vanadium: the structures of the decanuclear vanadium(IV) clusters [V10O16{CH3CH2C(CH2O)3}4]4- and [V10O13{CH3CH2C(CH2O)3}5]-Journal of the American Chemical Society, 1992
- A mixed valence heteropolyvanadate, K7Na[AsV4VV7VIV5O43H3]·7H2OInorganica Chimica Acta, 1992
- Synthesis and x-ray structures of two unprecedented heteropolymetalates [As3M3O15]3- (M = Mo, W) and [As6CoMo6O30]4-. First examples of linear triarsenate(III) and cyclic triarsenate(III)Inorganic Chemistry, 1991
- [H6As10Mo24O90]8⊖, a Heteropolyanion Comprising Two Linked Spherical Fragments, and Reduced Keggin Anions as Its Degradation ProductsAngewandte Chemie International Edition in English, 1990
- Heteropoly and Isopoly OxometalatesPublished by Springer Nature ,1983