Chemoenzymatic synthesis of (+)-(4E,15E)-docosa-4,15-dien-1-yn-3-ol, a component of the marine sponge Cribrochalina vasculum

Abstract
An acetylenic alcohol, (+)-(4E, 15E)-docosa-4,15-dien-1-yn-3-ol 1, isolated from the marine sponge Cribrochalina vasculum, was synthesized in highly enantiomerically pure form by lipase-catalysed transesterification with Novozym 435 (Candida antarctica).

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