Photoreduction of Hydroxo(tetramesitylporphinato)iron(III) in Aromatic Hydrocarbons and the Concurrent Generation of Hydroxyl Radical
- 1 January 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (1) , 153-156
- https://doi.org/10.1246/cl.1989.153
Abstract
Hydroxo(tetramesitylporphinato)iron(III) in degassed benzene, toluene, and ethylbenzene is confirmed to be reduced to the four coordinate ferrous complex upon irradiation with light λ > 300 nm. Production of diphenyl and solvent dependence of photoreduction rates support the concurrent generation of hydroxyl radical along with the ferrous complex production.Keywords
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