Zum Mechanismus der Hydroxylierungen mit molekularem Sauerstoff und Zinn(II)-Komplexen
Open Access
- 1 May 1969
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 24 (5) , 583-588
- https://doi.org/10.1515/znb-1969-0522
Abstract
Reduction of molecular oxygen by a stannous phosphate complex in aqueous solution leads to a new species of active oxygen capable of hydroxylating aliphatic and aromatic compounds. The hydroxylation reactions are shown to require two electrons per oxygen molecule reduced. The oxygen atom of the hydroxyl group is completely derived from molecular oxygen. This new mechanism has been proposed as a model for mixed function oxygenases.Keywords
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