Electroless Deposition of Certain Metal Oxides
- 1 January 1970
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 117 (5) , 615-618
- https://doi.org/10.1149/1.2407588
Abstract
Electroless deposition of α‐PbO2 films by oxidation of lead (II) acetate with peroxydisulfate is described. Investigations into the mechanism of this reaction show it to be a mixed electrolytic process with the two partial reactions and . The variation of mixed potential and growth rate with the pH of the electrolyte is studied and interpreted in terms of the pH dependence of both partial reactions. A mechanism of the reduction of is proposed.Keywords
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