The Synthesis and Decomposition of Novel Organophosphorus Complexants
- 1 October 1990
- journal article
- research article
- Published by Taylor & Francis in Separation Science and Technology
- Vol. 25 (13-15) , 1607-1627
- https://doi.org/10.1080/01496399008050412
Abstract
Aqueous soluble organic diphosphonic acids have been synthesized as aids in the extraction/recovery of metal values from nuclear waste, ground water, or hydrometallurgical processes. The reagents form aqueous soluble complexes at very low pH values (< 1). After use, these compounds do not represent an additional waste management problem as they are readily decomposed to innocuous materials (phosphoric acid and carbon dioxide) by warming and/or by the action of a mild oxidizing agent.Keywords
This publication has 14 references indexed in Scilit:
- Stability constants for europium(III) complexes with substituted methane diphosphonic acids in acid solutionsInorganica Chimica Acta, 1990
- HYDROXY AND/OR CARBOXY SUBSTITUTED PHOSPHONIC AND BISPHOSPHONIC ACIDS USABLE AS CORROSION AND SCALE INHIBITORSPhosphorus, Sulfur, and Silicon and the Related Elements, 1987
- Synthese von in 2‐ bzw. 3‐Stellung substituierten AlkandiphosphonsäurenZeitschrift für anorganische und allgemeine Chemie, 1979
- Umsetzungen von 1‐Aminoalkan‐1,1‐diphosphonsäuren mit salpetriger SäureZeitschrift für anorganische und allgemeine Chemie, 1979
- Base-induced rearrangement of ethane-2-chloro-1-hydroxy-1,1-diphosphonic acidThe Journal of Organic Chemistry, 1973
- Interaction of acylating agents and phosphorus(III) sources. I. Intermediacy of condensed species in the formation of (1-hydrocyethylidene) diphosphonic acidJournal of the American Chemical Society, 1972
- Herstellung von 1‐Aminoalkan‐1,1‐diphosphonsäurenZeitschrift für anorganische und allgemeine Chemie, 1972
- A General Method of Preparation of Tetramethyl Alkyl-1-hydroxy-1,1-diphosphonatesThe Journal of Organic Chemistry, 1971
- N.m.r. Study of the P-C(OH)-P to P-C-O-P Rearrangement: Tetraethyl 1-HydroxyalkylidenediphosphonatesJournal of the American Chemical Society, 1962
- Preparation of 1-HydroxyalkylidenediphosphonatesJournal of the American Chemical Society, 1956