ortho-Functionalisation of aryl ketones with alkenes; synthesis of 3-methylindene-2-carboxylates and 3-substituted-2-acetylthiophenes from η²-(o-acetylaryl)tetracarbonylmanganese compounds with alkenes in the presence of palladium(II)

1 January 1987

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 10,p. 761-762
https://doi.org/10.1039/c39870000761

Abstract

η²-(o-Acetylaryl)tetracarbonylmanganese compounds in the presence of Pd^II undergo new synthetically valuable coupling reactions with methyl acrylate, methyl vinyl ketone, acrylaldehyde, allyl alcohol, and acrylonitrile.

Keywords

ALKENES
TETRACARBONYLMANGANESE COMPOUNDS
METHYL ACRYLATE
COUPLING REACTIONS
NEW SYNTHETICALLY
UNDERGO NEW
ARYL KETONES

This publication has 0 references indexed in Scilit:

ortho-Functionalisation of aryl ketones with alkenes; synthesis of 3-methylindene-2-carboxylates and 3-substituted-2-acetylthiophenes from η2-(o-acetylaryl)tetracarbonylmanganese compounds with alkenes in the presence of palladium(II)

Abstract

Keywords

ortho-Functionalisation of aryl ketones with alkenes; synthesis of 3-methylindene-2-carboxylates and 3-substituted-2-acetylthiophenes from η²-(o-acetylaryl)tetracarbonylmanganese compounds with alkenes in the presence of palladium(II)