Exchange interactions in a series of novel heteronuclear basic carboxylate complexes containing two iron(III) ions and a divalent metal ion
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 796-797
- https://doi.org/10.1039/c39810000796
Abstract
Complexes [Fe2 IIIMIIO(MeCO2)6py3]py (M = Mg, Mn, Co, Ni, or Zn; py = pyridine), isomorphous(except for M = Ni) with the mixed-valence compounds [M3O(MeCO2)6py3]py (M = Mn or Fe), are reported; their magnetic properties provide new information about superexchange pathways in the trinuclear basic carboxylate system.Keywords
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