Collisional relaxation of vibrationally excited NO+(v) ions
- 1 August 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 83 (3) , 1032-1038
- https://doi.org/10.1063/1.449466
Abstract
Vibrational quenching rate constants have been measured for NO+(v) ions in collision with 17 neutral molecules. The dependence of the quenching rate constants on collision energy have been determined from near thermal energy up to ∼ 1 eV in some of these cases. The experimental results can be satisfactorily interpreted using a model of complex formation followed by vibrational predissociation with a rate constant of the order of 109–1010 s−1.Keywords
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