Linear relationship between bond length and reactivity
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 288-289
- https://doi.org/10.1039/c39790000288
Abstract
The two C–O bond lengths of the acetal group in a series of compounds derived from 2-phenoxytetrahydropyran vary with the aryloxy leaving group, and are linearly related to the free energy of activation for hydrolysis.Keywords
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