A collisional-radiative model applicable to argon discharge over a wide range of conditions. IV. Application to inductively coupled plasmas
- 14 March 1991
- journal article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 24 (3) , 309-317
- https://doi.org/10.1088/0022-3727/24/3/012
Abstract
For pt.III see ibid., vol.23, p.526 (1990). The extensive collisional-radiative model is applied to plasmas generated by a RF coil in an atmospheric argon flow in order to investigate excitation mechanisms and departures from local thermodynamic equilibrium in several spatial positions in these discharges. Computations are carried out for various sets of input parameters, such as the electron kinetic temperature Te, the atom temperature Ta, the electron number density ne, the ground-state atom population n1, the plasma column radius R and the escape factors Lambda mn and Lambda m, characterizing the non-equilibrium plasmas under consideration. The numerical modelling presented yields reliable information on the populations in the excited levels and on the validity of the so-called 'close to LTE concept' and the occurrence of an ionizing or a recombining regime in the locations investigated. The effect of the changes in the discharge parameters Te, Ta, ne, R and Lambda 1n on the excitation mechanisms, together with the role played by the inelastic atom-atom collisions and by the recombination flow of electrons from a continuum, are also shown.Keywords
This publication has 26 references indexed in Scilit:
- Electron temperature determination in LTE and non-LTE plasmasJournal of Quantitative Spectroscopy and Radiative Transfer, 1985
- An evaluation of ion-atom emission intensity ratios and local thermodynamic equilibrium in an argon inductively coupled plasmaSpectrochimica Acta Part B: Atomic Spectroscopy, 1984
- Influence of the Generator Frequency on the Spectral Characteristics of Inductively Coupled PlasmaApplied Spectroscopy, 1982
- On the significance of radiation trapping in the inductively coupled plasmaSpectrochimica Acta Part B: Atomic Spectroscopy, 1982
- Atomic fluorescence spectrometry with an inductively coupled plasma as atomization cell and pulsed hollow cathode lamps for excitationAnalytical Chemistry, 1981
- Plasma source mass spectrometry using an inductively coupled plasma and a high resolution quadrupole mass filterThe Analyst, 1981
- Kinetics of Ionization-Recombination of a Plasma and Population Density of Excited Ions. I. Equilibrium PlasmaJournal of the Physics Society Japan, 1979
- Influence of atom-atom collisions on thermal equilibrium in argon arc discharges at atmospheric pressureJournal of Physics D: Applied Physics, 1978
- An experimental study of a 1-kW, 50-MHz RF inductively coupled plasma with pneumatic nebulizer, and a discussion of experimental evidence for a non-thermal mechanismSpectrochimica Acta Part B: Atomic Spectroscopy, 1977
- Relaxation times for establishing quasi-stationary state populations in non-thermal plasmasPhysica B+C, 1976