α‐Hydroxymethylen‐verlängerte Aldehyde durch schonende Reduktion von Cyanhydrinen
- 12 July 1978
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 61 (5) , 1903-1911
- https://doi.org/10.1002/hlca.19780610532
Abstract
α‐Hydroxymethylene Elongated Aldehydes by Partial Reduction of CyanohydrinsAfter acetal‐protection of the hydroxy group, a number of cyanohydrins (derived from aldehydes or ketones) were reduced and hydrolysed to afford α‐hydroxyaldehydes in good yields. Other synthetically useful reactions of the intermediate α‐cyano and α‐formyl acetals have also been studied.Keywords
This publication has 38 references indexed in Scilit:
- Preparation and oxidation of .alpha.-hydroxyaldehydesThe Journal of Organic Chemistry, 1972
- The Total Synthesis of Sphingosine1Journal of the American Chemical Society, 1958
- Benzoin Condensations with Pivalaldehyde1Journal of the American Chemical Society, 1955
- Reduction of Organic Compounds by Mixed Hydrides. I. NitrilesJournal of the American Chemical Society, 1955
- THE SYNTHESIS OF SPHINGOSINEJournal of the American Chemical Society, 1954
- An Improved Method of Preparing Testosterone, Dihydrotestosterone and Some of their EstersJournal of the American Chemical Society, 1953
- Sodium Borohydride as a Reducing Agent for Sugar Lactones1Journal of the American Chemical Society, 1951
- The Controlled Sodium Amalgam Reduction of Aldonolactones and their Esters to Aldoses and an Improved Synthesis of D-Arabinose1Journal of the American Chemical Society, 1947
- Zur Darstellung mehrfach ungesättigter Nitrile und Aldehyde, II. MitteilungBerichte der deutschen chemischen Gesellschaft (A and B Series), 1939
- The Catalytic Hydrogenation of Aldonic Acid Delta and Gamma Lactones and of the AldosesJournal of the American Chemical Society, 1935