Synthesis and X-ray crystal structure of the rhenium(VII)tert-butylimido compound, [Re(NBut)2(η1-C5H5)]2(µ-C5H4)(µ-O)
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 181-182
- https://doi.org/10.1039/c39910000181
Abstract
The interaction of NaC5H5 in tetrahydrofuran with a diethyl ether solution of Re(NBut)3Cl gives rise to a compound [Re(NBut)2(η1-C5H5)]2(µ-C5H4)(µ-O) that has fluxional η1-C5H5 groups, non-equivalent ButN groups and a unique bridging C5H4 group; the structure has been elucidated by X-ray crystallography.Keywords
This publication has 8 references indexed in Scilit:
- Organometallic oxides: preparation and molecular and electronic structure of antiferromagnetic chromium complexes [(.eta.-C5H5)Cr(.mu.3-O)]4 and [(.eta.-C5H5)Cr]4(.mu.3-.eta.2-C5H4)(.mu.3-O)3Organometallics, 1990
- Multiple bonds between transition metals and main-group elements. 72. Organorhenium imido complexes: syntheses, structure, and reactivityOrganometallics, 1990
- t-Butylimido compounds of rhenium. X-ray crystal structures of [(ButN)2Re(μ-NBut)]2, (ButN)2ReCl3, (ButN)2ReCl2C6H5, (ButN)3Re(OSiMe3) and (ButN)3ReClPolyhedron, 1989
- Metal-metal multiple bonds. 20. Structural, kinetic, and theoretical studies of the reactivity of dimolybdenum .mu.-alkylidenes toward small molecules. Structures of M2(.mu.-CAr2), M2(.mu.-CAr2'), and M2(.mu.-.eta.1,.eta.2-iso-PrNC:CAr2') [M = Cp(or Cp')Mo(CO)2; Ar = p-tolyl, Ar2' = 2,2'-biphenylenyl, and Cp' = C5H4Me]Journal of the American Chemical Society, 1987
- Fluxional .eta.1-cyclopentadienyl compounds of main-group elementsChemical Reviews, 1986
- The μ3-cyclopentadienylidene ligand: X-ray structure of [Ru4(CO)5 {P(OMe)3}(μ3-C5H4)2(η-C5H5)2]Journal of Organometallic Chemistry, 1984
- Chemistry of .mu.-(.eta.1:.eta.5-cyclopentadienyl)-tris(.eta.-cyclopentadienyl)dititanium(Ti-Ti). 1. Synthesis and structural studiesJournal of the American Chemical Society, 1976
- Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and ironJournal of Inorganic and Nuclear Chemistry, 1956