Synthesis and X-ray crystal structure of the rhenium(VII)tert-butylimido compound, [Re(NBut)21-C5H5)]2(µ-C5H4)(µ-O)

Abstract
The interaction of NaC5H5 in tetrahydrofuran with a diethyl ether solution of Re(NBut)3Cl gives rise to a compound [Re(NBut)21-C5H5)]2(µ-C5H4)(µ-O) that has fluxional η1-C5H5 groups, non-equivalent ButN groups and a unique bridging C5H4 group; the structure has been elucidated by X-ray crystallography.

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