Dioxouranium(VI) Complexes with a Ter-Dentate Schiff Base Behaving as a Bi-Dentate Ligand
- 1 January 1978
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 8 (1) , 43-50
- https://doi.org/10.1080/00945717808057384
Abstract
The reactions of UO2X2 (X = Cl, I, NCS, NO3, 0.5 SO4, ClO4) with the potential ter-dentate Schiff base ligand (L), derived from the condensation of 2-amino 4-methyl pyridine with salicylaldehyde yield yellow or orange 1:2 solid complexes, all of which are non-electrolytes in C6H5NO2 or CH3NO2. This ter-dentate ligand behaves essentially as a bidentate one and the coordination number of uranium (VI) is 8 in all cases.Keywords
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