Bowl stacking in curved polynuclear aromatic hydrocarbons: crystal and molecular structure of cyclopentacorannulene

Abstract
Cyclopentacorannulene (dibenzo[ghi,mno]cyclopenta[cd]fluoranthene) exhibits long-range concave–convex bowl stacking in the crystal; its molecular structure is satisfactorily described by ab initio calculations at both HF/3-21G and HF/6-31G* levels.

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