Thermal stability of phosphonitrilic fluoroelastomers
- 1 February 1979
- journal article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 23 (3) , 765-775
- https://doi.org/10.1002/app.1979.070230312
Abstract
The thermal stability of the polymer prepared by substituting poly(dichlorophosphazene) with an excess of a 64/36 mole‐% mixture of the sodium salts of 2,2,2‐trifluoroethanol/2,2,3,3,4,4,5,5‐octafluoropentanol were studied by thermogravimetric and gel permeation chromatography techniques. The primary mode of degradation of this polymer was shown to be via random scission. The overall degradation reaction corresponds to quasi‐zero‐order kinetics.Keywords
This publication has 11 references indexed in Scilit:
- The Thermal Breakdown of Poly(diphenoxyphosphazene)Macromolecules, 1974
- Thermolysis of Poly[bis(trifluoroethoxy)phosphazene]Macromolecules, 1974
- Polyphosphazene elastomersJournal of Polymer Science: Polymer Symposia, 1974
- Phosphonitrilic Compounds. VI. High Molecular Weight Poly(alkoxy- and aryloxyphosphazenes)Inorganic Chemistry, 1966
- Synthesis of High Polymeric Alkoxy- and AryloxyphosphonitrilesJournal of the American Chemical Society, 1965
- Evaluation of rate constants from thermogravimetric dataJournal of Polymer Science Part A: General Papers, 1964
- Über den thermischen Abbau des polymeren PhosphornitrilchloridsAngewandte Chemie, 1959
- Rates of thermal degradation of polystyrene and polyethylene in a vacuumJournal of Polymer Science, 1952
- Depolymerization as a chain reactionJournal of Polymer Science, 1950
- SOME PRODUCTS OF THE TUBERCULOSIS BACILLUS.Journal of the American Chemical Society, 1897