Stereochemistry of the reductoisomerase and αβ-dihydroxyacid dehydratase-catalysed steps in valine and isoleucine biosynthesis. Observation of a novel tertiary ketol rearrangement
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 351-352
- https://doi.org/10.1039/c39740000351
Abstract
The reductoisomerase of Salmonella typhimurium has a requirement for the 2S-isomer of acetolactate (III, R = Me) while the αβ-dihydroxy-acid dehydratase has a requirement for the 2R configuration but is not stereoselective with respect to the configuration at C-3.Keywords
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