Photoinduced lnsertion of sulphur bridges into a CrSCr multiple bond, and X-ray crystal structure of (η5-C5H5)2Cr2(µ-S)2(µ-S2)
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1474-1475
- https://doi.org/10.1039/c39860001474
Abstract
Photoinduced insertion of sulphur ligands into the CrSCr multiple bond of (η5-C5H5)2Cr2(CO)4S provides a novel route to the new complex (η5-C5H5)2Cr2S4, which has one bidendate µ-S2 and two µ-S bridges symmetrically placed between the (η5-C5H5)Cr moieties.Keywords
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