Molecular Prussian Blue analogues: synthesis and structure of cubic Cr4Co4(CN)12 and Co8(CN)12 clusters
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1231-1232
- https://doi.org/10.1039/a802351d
Abstract
Reactions between [M(H2O)3(tacn)]3+ (M = Cr, Co) and [Co(CN)3(tacn)] are demonstrated to produce the molecular box clusters [Cr4Co4(CN)12(tacn)8]12+ and [Co8(CN)12- (tacn)8]12+ with core structures consisting of a single cubic unit excised from the Prussian Blue type framework.Keywords
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