JIS YB Lead Complex Perovskite Ferroelectric Material
- 1 September 1992
- journal article
- Published by IOP Publishing in Japanese Journal of Applied Physics
- Vol. 31 (9S) , 3124-3127
- https://doi.org/10.1143/jjap.31.3124
Abstract
Excess WO3 and higher sintering temperature were used for decreasing the temperature dependence of the dielectric constant in Pb(Mg1/3Nb2/3)O3-PbTiO3-Pb(Mg1/2W1/2)O3 ternary systems. Under some conditions, materials with both JIS YB specifications (dielectric constant change less than 10% over the temperature range from -25 to 85°C) and high dielectric constant, 5000-7400, were obtained. In the materials, core-shell-like distributions of B-site components were observed. These core-shell structures consist of W-rich regions and Ti, Nb-rich regions. In the compositions containing 2% WO3, sintered at 1150°C, core-shell-like domain structures are observed. The fringe pattern corresponded to the Ti, Nb-rich region, and superlattice electron diffraction spots indicating B-site ordering were observed in the W-rich region. In addition, the amounts of WO3 varied the appearance of the core-shell structure.Keywords
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- Fabrication of perovskite lead magnesium niobatePublished by Elsevier ,2003