The Temperature Dependence of Transition State Volumes in Hydrolysis Reactions
Open Access
- 1 December 1971
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 49 (23) , 3840-3845
- https://doi.org/10.1139/v71-641
Abstract
The temperature dependence of the transition state volume, [Formula: see text], in a number of hydrolysis reactions is derived from pressure/rate data and partial volume temperature dependence. The values obtained for [Formula: see text] vary from near zero for p-methylbenzyl chloride to about 0.3 ml mol−1 deg−1 for isopropyl bromide. The interpretation of the experimental and derived values for these hydrolyses is discussed in terms of charge development with accompanying solvation effects about the solute.Keywords
This publication has 0 references indexed in Scilit: