Regio- and stereo-specificity of nucleophilic attack on steroidal π-allylpalladium complexes
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2595-2597
- https://doi.org/10.1039/p19820002595
Abstract
Reaction of α- and β-1–3-η-type steroidal π-allylpalladium complexes with AcOK yielded products resulting from trans-attack on the side opposite to the co-ordinated palladium, while reaction of steroidal olefins with PdCl2CuCl2-AcOK/AcOH afforded products arising from cis-attack.Keywords
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