Syntheses with 2-Furylmagnesium Bromides. I. Synthesis of Rosefuran and Sesquirosefuran
- 1 July 1977
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 50 (7) , 1903-1904
- https://doi.org/10.1246/bcsj.50.1903
Abstract
The preparation and reactions of 2-furylmagnesium bromide and 3-methyl-2-furylmagnesium bromide (4b) have been studied. Activated 90% magnesium–copper alloy was used to prepare the Grignard reagents. The reaction of 1-bromo-3-methyl-2-butene with 4b gave rosefuran in a 40% yield; that of geranyl bromide with 4b gave sesquirosefuran in a 26% yield.Keywords
This publication has 5 references indexed in Scilit:
- Synthesis of SesquirosefuranBulletin of the Chemical Society of Japan, 1974
- Synthesis of rosefuran and dehydroelsholtzioneThe Journal of Organic Chemistry, 1968
- The Synthesis and Proton Magnetic Resonance Spectra of Some Brominated Furans1The Journal of Organic Chemistry, 1964
- THE SIMPLE HALOGEN DERIVATIVES OF FURANJournal of the American Chemical Society, 1930
- A QUALITATIVE COLOR TEST FOR THE GRIGNARD REAGENTJournal of the American Chemical Society, 1925