ENDOR Experiments on Free Radicals in Solution

Abstract
The ENDOR spectrum of Coppinger's radical was obtained by a 20–30 watt rf, which was frequency-modulated at 6.5 kHz in the room temp. - liq. N2 temp. range. The frequency of magnetic modulation was 100 kHz or 80 Hz. Details of the ENDOR spectrometer are given, and the temperature and concentration dependence of the ENDOR signal intensity are examined. In employing high frequency magnetic field modulation, the passage condition must be taken into consideration.

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