Caged oxoanionsElectronic supplementary information (ESI) available: tables of protonation and stability constants and graphs of species formation as a function of pH for R3Bm + malonate and R3P + malonate and the distribution of protonated species as a function of pH for Me6R3Bm. See http://www.rsc.org/suppdata/cs/b2/b200672n/
- 14 July 2003
- journal article
- introductory reviews
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 32 (5) , 309-325
- https://doi.org/10.1039/b200672n
Abstract
The association between azacryptand hosts and oxoanion guests is reviewed. Positively charged hosts are the most effective; we focus on protonated azacryptands. Assessment of quantitative data suggests an anion cryptate effect and provides clear evidence for charge-based selectivity. Crystal structures show both cavity and cleft binding sites for anions within the series of cryptands studied. These two binding modes exhibit different pH dependence, offering the possibility for design of monitoring/clean-up strategies based on a variation of appropriate host(s) and pH conditions.Keywords
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